1894 Brewer’s / M / Manna of St. Nicholas of Bari
The name given to a colourless and tasteless poison, sold in phials by a woman of Italy named Tofani, who confessed to having poisoned six hundred persons by this liquid.
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Entry taken from Dictionary of Phrase and Fable, edited by the Rev. E. Cobham Brewer, LL.D. and revised in 1895.