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One who in debauchery surpasses the rest of his companions, a blood or choice spirit. There are in London divers lodges or societies of Bucks, formed in imitation of the Free Masons: one was held at the Rose, in Monkwell-street, about the year 1705. The president is styled the Grand Buck. A buck sometimes signifies a cuckold.
Definition taken from The 1811 Dictionary of the Vulgar Tongue, originally by Francis Grose.
Buck Bail * Buck’s FaceNathan Bailey's 1736 Dictionary of canting and thieving slang
John S. Farmer's collection of canting songs and slang rhymes
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Francis Grose was independently wealthy, having inherited money from his father, a jeweller. Finding himself overspending, he published a number of books; his Provincial Glossary seems to have been the starting-point for the Vulgar Tongue reproduced here.